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Some interesting pyrrole derivatives were synthesized in moderate to high yields by coupling of 4- hydroxyproline with isatins, 11H-indeno[1,2-b]quinoxalin-11-ones, quinones and 9H-fluoren-9-one, in the presence of catalytic amount of Alum supported on silica gel (Alum-SiO2), under microwave irradiation.