Synthetic Studies of Superstolide A: A Carbohydrate Based Synthesis of the C21-C26 Segment

Rita Pal; Hasibur Rahaman; D. K. Mohapatra; Mukund K. Gurjar

doi:10.2174/157017810793811704

ISSN: 1570-1786
E-ISSN: 1875-6255

Synthetic Studies of Superstolide A: A Carbohydrate Based Synthesis of the C21-C26 Segment
By Rita Pal, Hasibur Rahaman, D. K. Mohapatra and Mukund K. Gurjar
Source: Letters in Organic Chemistry, Volume 7, Issue 8, Dec 2010, p. 657 - 660
DOI: https://doi.org/10.2174/157017810793811704
- Available online: 01 Dec 2010

Abstract

The synthesis of C21-C26 fragment of superstolide A, starting from D-glucose diacetonide, involving regioselective ring opening of epoxide by Grignard reagent and regioselective stereospecefic hydroboration oxidation has been described.

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2010-12-01

2025-09-19

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Article Type: Research Article

Keyword(s): alcohol; azido; BBN; benzyl ether; C21-C26; Carbohydrate; Chiral pool; Cleavage; compound; CuCN; D-glucose diacetonide; Debenzylation; epoxidation; Grignard reagent; hydroboration oxidation; hydroxyl group; mesylation; methanolic HCl; Neosiphonia superstes; Oxidative cleavage; PDC oxidation; PMB; polyketide; Potent cytotoxic; Regioselective epoxide opening; selectively; Stereoselective hydroborationoxidation; Superstolide A; tosylation

Synthetic Studies of Superstolide A: A Carbohydrate Based Synthesis of the C21-C26 Segment

Abstract

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