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2000
Volume 7, Issue 7
  • ISSN: 1570-1786
  • E-ISSN: 1875-6255

Abstract

Enantioselective ring-opening reaction of meso-epoxides with arylselenols using a chiral (salen)Ti(IV) complex as catalyst was realized, and 1,2- arylseleno alcohols were obtained in good yields and up to 80 % ee.

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/content/journals/loc/10.2174/157017810793362226
2010-10-01
2025-09-10

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  • Article Type:     Research Article
Keyword(s): 2-(naphthylseleno)-1-cyclohexanol; 2-(phenylseleno)-1-cyclohexanol; 2-(phenylseleno)-1-cyclopentanol; 3-(phenylseleno)-2-butylol; Arylselenols; asymmetric catalysis; Bruker AMX-300 spectrometer; chiral Chiralcel OD-H column; epoxides; Grignard reagents; HPLC; Kozlowski's modular bifunctional salen ligands; mass spectrometer; mercaptoalcohols; NMR; ring-opening reaction; Ring-Opening Reactiona; RN3; RNH2; ROH; RSH; scandium-bipyridine complex; Schlenk techniques; selenophenol; TMSCN

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