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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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The Copper(I) Chloride-Catalyzed Reaction of Ketene Silyl Acetals or Silyl Enol Ethers with α-Halogen Substituted Allylsilanes to Form Carbonyl Compounds Bearing Vinylsilane Functionality
- Source: Letters in Organic Chemistry, Volume 4, Issue 3, Apr 2007, p. 181 - 184
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- 01 Apr 2007
Abstract
The CuCl-catalyzed reaction of (1-bromo-2-propenyl)trimethylsilane with silyl enol ethers or ketene silyl acetals in a CH3CN solution was studied. A new method for the preparation of ketone and ester derivatives bearing a vinylsilane functionality at the γ-position was developed.
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