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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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First Immobilization of Chiral Menthol-Derived Picoline on Solid Support and Evaluation for Asymmetric Catalysis
- Source: Letters in Organic Chemistry, Volume 4, Issue 3, Apr 2007, p. 175 - 180
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- 01 Apr 2007
Abstract
The first polystyrene-supported chiral picolyl menthol has been prepared via a selective hydrosilylation route and evaluated for asymmetric catalysis. The new catalyst was efficient and reusable in the test reaction of diethylzinc addition to benzaldehyde at room temperature. The enantioselectivity was comparable with that of the soluble counterpart.
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