Letters in Organic Chemistry [Calixarene-Based Hyperbranched Molecules with 'Tame' and 'Sen' Ligand Cores

Mouna Mahouachi; Rym Abidi; Yang Kim; Sang H. Lee; Jong H. Jung; Jong S. Kim; Jacques Vicens

doi:10.2174/157017806777828439

ISSN: 1570-1786
E-ISSN: 1875-6255

Letters in Organic Chemistry [Calixarene-Based Hyperbranched Molecules with 'Tame' and 'Sen' Ligand Cores
Authors: Mouna Mahouachi¹, Rym Abidi², Yang Kim³, Sang H. Lee⁴, Jong H. Jung⁵, Jong S. Kim⁶ and Jacques Vicens⁷
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¹ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ² Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ³ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ⁴ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ⁵ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ⁶ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France. ⁷ Ecole Chimie Polymeres Materiaux, Laboratoire de Conception Moleculaire, associe au CNRS, 25 rue ecquerel, F-67087 Strasbourg, Cedex 2, France.
Source: Letters in Organic Chemistry, Volume 3, Issue 6, Jun 2006, p. 426 - 429
DOI: https://doi.org/10.2174/157017806777828439
- Available online: 01 Jun 2006

Abstract

Reactions between tripodal CH3C(CH2NH2)3 = 'tame' and CH3C(CH2NHCH2CH2NH2)3 = 'sen' with the monomethoxycarbonylmethyl ether 1 lead to the ready isolation of tame-dicalix 2, tame-tricalix 3 and sentricalix 4. Studies of complex formation of 3 and 4 with Zn(II) showed that 'tame' residue is incapable of coordinating the metal in its N3 donor site, while Zn(II) is preferentially coordinated in the carbomethoxyamido functions and two hydroxyl groups of the calix[4]units of 4.

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2006-06-01

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Article Type: Research Article

Keyword(s): Calixarenes; hyperbranched molecules; tripodal ligands; Zn-complexation

Letters in Organic Chemistry [Calixarene-Based Hyperbranched Molecules with 'Tame' and 'Sen' Ligand Cores

Abstract

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