SiO2/N2O4 and Fe(NO3)3.9H2O/H3PMo12O40.xH2O Systems as Powerful Oxidants for Removal of Cyclic Dioxalanes and Dithianes

Mohammad A. Zolfigol; Iraj Mohammadpoor-Baltork; Ardeshir Khazae; Morteza Shiri; Zahra Tanbakouchian

doi:10.2174/157017806776114676

ISSN: 1570-1786
E-ISSN: 1875-6255

SiO2/N2O4 and Fe(NO3)3.9H2O/H3PMo12O40.xH2O Systems as Powerful Oxidants for Removal of Cyclic Dioxalanes and Dithianes
Authors: Mohammad A. Zolfigol¹, Iraj Mohammadpoor-Baltork², Ardeshir Khazae³, Morteza Shiri⁴ and Zahra Tanbakouchian⁵
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¹ Chemistry Department, College of Sciences, Bu-Ali Sina University, Hamadan, 65174, Iran. ² Chemistry Department, College of Sciences, Bu-Ali Sina University, Hamadan, 65174, Iran. ³ Chemistry Department, College of Sciences, Bu-Ali Sina University, Hamadan, 65174, Iran. ⁴ Chemistry Department, College of Sciences, Bu-Ali Sina University, Hamadan, 65174, Iran. ⁵ Chemistry Department, College of Sciences, Bu-Ali Sina University, Hamadan, 65174, Iran.
Source: Letters in Organic Chemistry, Volume 3, Issue 4, Apr 2006, p. 305 - 308
DOI: https://doi.org/10.2174/157017806776114676
- Available online: 01 Apr 2006

Abstract

SiO2/N2O4 system was used as an efficient oxidant for the conversion of cyclic dioxalanes and dithianes to parent carbonyl compound in CH2Cl2 at room temperature. We also found Fe(NO3)3.9H2O/H3PMo12O40.xH2O could be used as a powerful oxidation complex for similar transformations at room temperature under solvent free conditions.

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2006-04-01

2025-09-06

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Article Type: Research Article

Keyword(s): deprotection; Dinitrogen tetroxide; dioxalanes; dithianes; ferric nitrate; heteropoly acids; molibdatophosphoric acid

SiO2/N2O4 and Fe(NO3)3.9H2O/H3PMo12O40.xH2O Systems as Powerful Oxidants for Removal of Cyclic Dioxalanes and Dithianes

Abstract

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