One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)

Diver Sellanes; Laura Scarone; Eduardo Manta; Peter Wipf; Gloria Serra

doi:10.2174/157017806776114621

ISSN: 1570-1786
E-ISSN: 1875-6255

One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)
Authors: Diver Sellanes¹, Laura Scarone², Eduardo Manta³, Peter Wipf⁴ and Gloria Serra⁵
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¹ Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay. ² Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay. ³ Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay. ⁴ Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay. ⁵ Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay.
Source: Letters in Organic Chemistry, Volume 3, Issue 4, Apr 2006, p. 309 - 312
DOI: https://doi.org/10.2174/157017806776114621
- Available online: 01 Apr 2006

Abstract

Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes. Similar results are described for other aliphatic and aromatic aldehydes.

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2006-04-01

2025-09-05

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Article Type: Research Article

Keyword(s): 3-diene; allyltriphenylphosphonium; Garner's aldehyde; Wittig reactions; β-hydroxy-1

One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)

Abstract

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