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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Reaction of 2-Diazo-1,2-diphenylethanone with 2-[(Arylimino)methyl]phenols
- Source: Letters in Organic Chemistry, Volume 3, Issue 3, Mar 2006, p. 212 - 213
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- 01 Mar 2006
Abstract
An equimolar reaction of the 2-diazo-1,2-diphenylethanone with 2-[(arylimino)methyl]phenols affords 2-[(arylimino)methyl]phenyl-2,2-diphenylacetates and 2-azetidinones. The products have been characterized on the basis of satisfactory spectral data. The regiochemistry of the reaction of hydroxyl and imino group towards diphenylketene, generated from thermal decomposition of the 2-diazo-1,2- diphenylethanone, has been observed to depend on the substituents on N-phenyl ring.
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