New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens

Frederic Leroux; Nathalie Nicod; Laurence Bonnafoux; Berengere Quissac; Francoise Colobert

doi:10.2174/157017806775224279

ISSN: 1570-1786
E-ISSN: 1875-6255

New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens
Authors: Frederic Leroux¹, Nathalie Nicod², Laurence Bonnafoux³, Berengere Quissac⁴ and Francoise Colobert⁵
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¹ Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France. ² Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France. ³ Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France. ⁴ Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France. ⁵ Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France.
Source: Letters in Organic Chemistry, Volume 3, Issue 2, Feb 2006, p. 165 - 169
DOI: https://doi.org/10.2174/157017806775224279
- Available online: 01 Feb 2006

Abstract

Regioselective halogen/lithium permutation reactions were carried out on polybrominated biaryls. Thus, highly functionalized, dissymetrically substituted biaryls become easily accessible on gram scale.

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2006-02-01

2025-11-01

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Article Type: Research Article

Keyword(s): chromatographic comparison; Complexation; disproportionation; halogen; isoquinoline; polar organometallic methods

New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens

Abstract

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