Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System

Hsing-Jang Liu; Daqing Sun; Floria Roa-Gutierrez; Kak-Shan Shia

doi:10.2174/1570178054038966

ISSN: 1570-1786
E-ISSN: 1875-6255

Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System
Authors: Hsing-Jang Liu¹, Daqing Sun², Floria Roa-Gutierrez³ and Kak-Shan Shia⁴
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¹ Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013, ROC. ² Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013, ROC. ³ Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013, ROC. ⁴ Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013, ROC.
Source: Letters in Organic Chemistry, Volume 2, Issue 4, Jun 2005, p. 364 - 366
DOI: https://doi.org/10.2174/1570178054038966
- Available online: 01 Jun 2005

Abstract

The polyene cyclization promoted by the cross conjugated α-carbomethoxy enone system has been successfully applied to facilitate the construction of the hydridane and hydroazulene framework containing a high level of functionalization.

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2005-06-01

2025-09-13

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Article Type: Review Article

Keyword(s): bicyclic aliphatic compounds; cyclization; hydridanes; hydroazulenes; polyenes; steroidal compounds

Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System

Abstract

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