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2000
Volume 13, Issue 2
  • ISSN: 2213-3461
  • E-ISSN: 2213-347X

Abstract

Mercury is a pollutant of concern due to its negative influence on the environment and human health. Hydrotalcites, also known as layered double hydroxides, have attracted tremendous attention over the last few years in several fields such as healthcare and environmental remediation. Herein, a novel hybrid ZnAlLDH was synthesized to test its effect on mercury adsorption capacity. ZnAl-CO/LDH synthesized using the co-precipitation method is grafted with a new phosphonic acid named2-(bis(phosphonomethyl)amino)ethane-1-sulfonic acid synthesized in our laboratory. Materials were characterized using textural, structural and morphological analysis. Mercury removal is measured by adsorption tests under relevant conditions. Parameters affecting the extraction process such as stirring speed, adsorbent dose, Hg2+ concentration, pH, ionic strength and temperature were fully studied and discussed. In effect, LDH intercalation with phosphonic acid and the optimization of mercury adsorption conditions improved the adsorption capacity of the prepared material by ca. 40%.87% of Hg2+ was successfully removed from aqueous solution. The hybrid LDH was also investigated in antibacterial and antifungal activities against Gram-negative ( (ATCC 25922), (A22), (ATCC27853) and (ATCC17978)), Gram-positive ( (ATCC11778), (ATCC25922), (ATCC43300) and (ATCC25923)) bacteria and (ATCC26790) fungus.

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References

  1. YangJ. HouB. WangJ. TianB. BiJ. WangN. LiX. HuangX. Nanomaterials for the removal of heavy metals from wastewater.Nanomaterials20199342410.3390/nano9030424 30871096
     [Google Scholar]
  2. RehmanK. FatimaF. WaheedI. AkashM.S.H. Prevalence of exposure of heavy metals and their impact on health consequences.J. Cell. Biochem.2018119115718410.1002/jcb.26234 28643849
     [Google Scholar]
  3. MurataK. KaritaK. Minamata disease. Overcoming Environmental Risks to Achieve Sustainable Development Goals.Springer202291910.1007/978‑981‑16‑6249‑2_2
     [Google Scholar]
  4. AlbatrniH. QiblaweyH. El-NaasM.H. Comparative study between adsorption and membrane technologies for the removal of mercury.Separ. Purif. Tech.202125711783310.1016/j.seppur.2020.117833
     [Google Scholar]
  5. YuJ.G. YueB.Y. WuX.W. LiuQ. JiaoF.P. JiangX.Y. ChenX.Q. Removal of mercury by adsorption: A review.Environ. Sci. Pollut. Res. Int.20162365056507610.1007/s11356‑015‑5880‑x 26620868
     [Google Scholar]
  6. DoniaA.M. AtiaA.A. AbouzayedF.I. Preparation and characterization of nano-magnetic cellulose with fast kinetic properties towards the adsorption of some metal ions.Chem. Eng. J.2012191223010.1016/j.cej.2011.08.034
     [Google Scholar]
  7. TadesseA. HagosM. RamaDeviD. BasavaiahK. BelachewN. Fluorescent-nitrogen-doped carbon quantum dots derived from citrus lemon juice: Green synthesis, mercury (II) ion sensing, and live cell imaging.ACS Omega2020583889389810.1021/acsomega.9b03175 32149215
     [Google Scholar]
  8. RahmanZ. SinghV.P. The relative impact of toxic heavy metals (THMs) (arsenic (As), cadmium (Cd), chromium (Cr)(VI), mercury (Hg), and lead (Pb)) on the total environment: An overview.Environ. Monit. Assess.2019191741910.1007/s10661‑019‑7528‑7 31177337
     [Google Scholar]
  9. CaiF. ZhuQ. ZhaoK. DengA. LiJ. Multiple signal amplified electrochemiluminescent immunoassay for Hg2+ using graphene-coupled quantum dots and gold nanoparticles-labeled horseradish peroxidase.Environ. Sci. Technol.20154985013502010.1021/acs.est.5b00690 25799039
     [Google Scholar]
  10. ChaiW.S. CheunJ.Y. KumarP.S. MubashirM. MajeedZ. BanatF. HoS-H. ShowP.L. A review on conventional and novel materials towards heavy metal adsorption in wastewater treatment application.J. Clean. Prod.202129612658910.1016/j.jclepro.2021.126589
     [Google Scholar]
  11. KaykhaiiM. SasaniM. MarghzariS. Removal of dyes from the environment by adsorption process.Chem. Mater. Eng.201862313510.13189/cme.2018.060201
     [Google Scholar]
  12. HananeZ. Preparation, characterization and antibacterial applications of ZnAl-LDH with the diaminododecylphosphonic acid intercalation.South Asian J. Exp. Biol.202111560060410.38150/sajeb.11(5).p600‑604
     [Google Scholar]
  13. AbderrazekK. NajouaF.S. SrasraE. Synthesis and characterization of [Zn–Al] LDH: Study of the effect of calcination on the photocatalytic activity.Appl. Clay Sci.201611922923510.1016/j.clay.2015.10.014
     [Google Scholar]
  14. JadhavA.L. YadavG.D. A Green process for selective hydrolysis of cinnamaldehyde in water to natural benzaldehyde by using Ti and Zn modified hydrotalcites as catalysts.Curr. Green Chem.20196324225410.2174/2213346106666191021105244
     [Google Scholar]
  15. TranH.N. NguyenD.T. LeG.T. TomulF. LimaE.C. WooS.H. SarmahA.K. NguyenH.Q. NguyenP.T. NguyenD.D. NguyenT.V. VigneswaranS. VoD.V.N. ChaoH.P. Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents: A systematic in-depth review.J. Hazard. Mater.201937325827010.1016/j.jhazmat.2019.03.018 30925385
     [Google Scholar]
  16. ChmielewskáE. Current progress in designing environmental adsorbents.Curr. Green Chem.2019613810.2174/221334610601190329164505
     [Google Scholar]
  17. YangZ. ZhangC. ZengG. TanX. WangH. HuangD. YangK. WeiJ. MaC. NieK. Design and engineering of layered double hydroxide based catalysts for water depollution by advanced oxidation processes: A review.J. Mater. Chem. A Mater. Energy Sustain.2020884141417310.1039/C9TA13522G
     [Google Scholar]
  18. LeK. WangZ. WangF. WangQ. ShaoQ. MurugadossV. WuS. LiuW. LiuJ. GaoQ. GuoZ. Sandwich-like NiCo layered double hydroxide/reduced graphene oxide nanocomposite cathodes for high energy density asymmetric supercapacitors.Dalton Trans.201948165193520210.1039/C9DT00615J 30896012
     [Google Scholar]
  19. XiangX. PanF. LiY. A review on adsorption-enhanced photoreduction of carbon dioxide by nanocomposite materials.Adv. Compos. Hybrid Mater.20181163110.1007/s42114‑017‑0001‑6
     [Google Scholar]
  20. PanD. GeS. ZhaoJ. TianJ. ShaoQ. GuoL. MaiX. WuT. MurugadossV. LiuH. DingT. AngaiahS. GuoZ. Synthesis and characterization of ZnNiIn layered double hydroxides derived mixed metal oxides with highly efficient photoelectrocatalytic activities.Ind. Eng. Chem. Res.201958283684810.1021/acs.iecr.8b04829
     [Google Scholar]
  21. Taviot-GuéhoC. PrévotV. ForanoC. RenaudinG. MoustyC. LerouxF. Tailoring hybrid layered double hydroxides for the development of innovative applications.Adv. Funct. Mater.20182827170386810.1002/adfm.201703868
     [Google Scholar]
  22. CuiJ. LiZ. WangG. GuoJ. ShaoM. Layered double hydroxides and their derivatives for lithium–sulfur batteries.J. Mater. Chem. A Mater. Energy Sustain.2020845237382375510.1039/D0TA08573A
     [Google Scholar]
  23. LiuX. HuT. LinG. WangX. ZhuY. LiangR. DuanW. WeiM. The synthesis of a DHAD/ZnAlTi-LDH composite with advanced UV blocking and antibacterial activity for skin protection.RSC Advances202010179786979010.1039/D0RA00572J 35498563
     [Google Scholar]
  24. XieP. LiY. HouQ. SuiK. LiuC. FuX. ZhangJ. MurugadossV. FanJ. WangY. FanR. GuoZ. Tunneling-induced negative permittivity in Ni/MnO nanocomposites by a bio-gel derived strategy.J. Mater. Chem. C Mater. Opt. Electron. Devices2020893029303910.1039/C9TC06378A
     [Google Scholar]
  25. ZhuS. Asim KhanM. WangF. BanoZ. XiaM. Rapid removal of toxic metals Cu2+ and Pb2+ by amino trimethylene phosphonic acid intercalated layered double hydroxide: A combined experimental and DFT study.Chem. Eng. J.202039212371110.1016/j.cej.2019.123711
     [Google Scholar]
  26. AsiabiH. YaminiY. ShamsayeiM. Using cobalt/chromium layered double hydroxide nano-sheets as a novel packed in-tube solid phase microextraction sorbent for facile extraction of acidic pesticides from water samples.New J. Chem.201842129935994410.1039/C8NJ00372F
     [Google Scholar]
  27. YuS. LiuY. AiY. WangX. ZhangR. ChenZ. ChenZ. ZhaoG. WangX. Rational design of carbonaceous nanofiber/Ni- Al layered double hydroxide nanocomposites for high-efficiency removal of heavy metals from aqueous solutions.Environ. Pollut.2018242Pt A11110.1016/j.envpol.2018.06.03129957540
     [Google Scholar]
  28. SeftelE.M. PopoviciE. MertensM. WitteK.D. TendelooG.V. CoolP. VansantE.F. Zn–Al layered double hydroxides: Synthesis, characterization and photocatalytic application.Microporous Mesoporous Mater.20081131-329630410.1016/j.micromeso.2007.11.029
     [Google Scholar]
  29. SalakA.N. LisenkovA.D. ZheludkevichM.L. FerreiraM.G.S. Carbonate-free Zn-Al (1: 1) layered double hydroxide film directly grown on zinc-aluminum alloy coating.ECS Electrochemistry Letters201331C9C1110.1149/2.008401eel
     [Google Scholar]
  30. WeiM. ShiS. WangJ. LiY. DuanX. Studies on the intercalation of naproxen into layered double hydroxide and its thermal decomposition by in situ FT-IR and in situ HT-XRD.J. Solid State Chem.200417772534254110.1016/j.jssc.2004.03.041
     [Google Scholar]
  31. ChakrabortyM. DasguptaS. SoundrapandianC. ChakrabortyJ. GhoshS. MitraM.K. BasuD. Methotrexate intercalated ZnAl-layered double hydroxide.J. Solid State Chem.201118492439244510.1016/j.jssc.2011.07.015
     [Google Scholar]
  32. QiF. ZhangX. LiS. A novel method to get methotrexatum/layered double hydroxides intercalation compounds and their release properties.J. Phys. Chem. Solids20137481101110810.1016/j.jpcs.2013.03.005
     [Google Scholar]
  33. GaoX. LeiL. O’HareD. XieJ. GaoP. ChangT. Intercalation and controlled release properties of vitamin C intercalated layered double hydroxide.J. Solid State Chem.201320317418010.1016/j.jssc.2013.04.028
     [Google Scholar]
  34. KuehnT. PoellmannH. Synthesis and characterization of Zn-Al layered double hydroxides intercalated with 1-to 19-carbon carboxylic acid anions.Clays Clay Miner.201058559660510.1346/CCMN.2010.0580502
     [Google Scholar]
  35. KhanA.I. O’HareD. Intercalation chemistry of layered double hydroxides: Recent developments and applications.J. Mater. Chem.200212113191319810.1039/B204076J
     [Google Scholar]
  36. Taviot-GuehoC. IllaikA. VuillermozC. CommereucS. VerneyV. LerouxF. LDH–dye hybrid material as coloured filler into polystyrene: Structural characterization and rheological properties.J. Phys. Chem. Solids2007685-61140114610.1016/j.jpcs.2007.03.003
     [Google Scholar]
  37. BotanR. de Bona SartorS. X-ray diffraction analysis of layered double hydroxide polymer nanocomposites.Layered Double Hydroxide Polymer Nanocomposites.Elsevier202020522910.1016/B978‑0‑08‑101903‑0.00005‑2
     [Google Scholar]
  38. StarukhH. LevytskaS. The simultaneous anionic and cationic dyes removal with Zn Al layered double hydroxides.Appl. Clay Sci.201918010518310.1016/j.clay.2019.105183
     [Google Scholar]
  39. LiJ. YanL. YangY. ZhangX. ZhuR. YuH. Insight into the adsorption mechanisms of aqueous hexavalent chromium by EDTA intercalated layered double hydroxides: XRD, FTIR, XPS, and zeta potential studies.New J. Chem.20194340159151592310.1039/C9NJ03479J
     [Google Scholar]
  40. HuangQ. WangY. ZhouB. WeiY. GaoF. FujitaT. The effect of ZnAl-LDHs-CO3 on the corrosion behaviour of Zn-5Al alloys in 3.5wt.% NaCl solution.Corros. Sci.202117910916510.1016/j.corsci.2020.109165
     [Google Scholar]
  41. ZhouJ. YangS. YuJ. ShuZ. Novel hollow microspheres of hierarchical zinc–aluminum layered double hydroxides and their enhanced adsorption capacity for phosphate in water.J. Hazard. Mater.201119231114112110.1016/j.jhazmat.2011.06.013 21719194
     [Google Scholar]
  42. IyiN. EbinaY. SasakiT. Synthesis and characterization of water-swellable LDH (layered double hydroxide) hybrids containing sulfonate-type intercalant.J. Mater. Chem.201121228085809510.1039/c1jm10733j
     [Google Scholar]
  43. PrevotV. TokudomeY. 3D hierarchical and porous layered double hydroxide structures: An overview of synthesis methods and applications.J. Mater. Sci.20175219112291125010.1007/s10853‑017‑1067‑9
     [Google Scholar]
  44. SantosR.M.M. TrontoJ. BrioisV. SantilliC.V. Thermal decomposition and recovery properties of ZnAl–CO3 layered double hydroxide for anionic dye adsorption: Insight into the aggregative nucleation and growth mechanism of the LDH memory effect.J. Mater. Chem. A Mater. Energy Sustain.201752099981000910.1039/C7TA00834A
     [Google Scholar]
  45. MouridE.H. LakraimiM. BenazizL. CherkaouiM. Removal efficiency of lipid-regulating drug clofibric acid from the aquatic environment by calcined anionic clay ZnAl-CO3.Chem. Biochem. Eng. Q.2020342799210.15255/CABEQ.2020.1797
     [Google Scholar]
  46. KangG.H. ParkI.K. Reconstruction and intercalating anion exchange of ZnAl-layered double hydroxide.Ceram. Int.20224833030303610.1016/j.ceramint.2021.10.078
     [Google Scholar]
  47. JeonC.W. LeeS.S. ParkI.K. Abnormal temperature-dependent electrical conduction in ZnAl-layered double hydroxide nanostructures.Appl. Surf. Sci.202153814812210.1016/j.apsusc.2020.148122
     [Google Scholar]
  48. ZhuS. ChenY. KhanM.A. XuH. WangF. XiaM. In-depth study of heavy metal removal by an etidronic acid-functionalized layered double hydroxide.ACS Appl. Mater. Interfaces20221457450746310.1021/acsami.1c22035 35077125
     [Google Scholar]
  49. ZhuS. KhanM.A. KamedaT. XuH. WangF. XiaM. YoshiokaT. New insights into the capture performance and mechanism of hazardous metals Cr3+ and Cd2+ onto an effective layered double hydroxide based material.J. Hazard. Mater.202242612806210.1016/j.jhazmat.2021.128062 34929593
     [Google Scholar]
  50. NaushadM. VasudevanS. SharmaG. KumarA. ALOthman, Z.A. Adsorption kinetics, isotherms, and thermodynamic studies for Hg2+ adsorption from aqueous medium using alizarin red-S-loaded amberlite IRA-400 resin.Desalination Water Treat.20165739185511855910.1080/19443994.2015.1090914
     [Google Scholar]
  51. GanzaghM.A.A. YousefpourM. TaherianZ. The removal of mercury (II) from water by Ag supported on nanomesoporous silica.J. Chem. Biol.20169412714210.1007/s12154‑016‑0157‑5 27698950
     [Google Scholar]
  52. HadiP. ToM.H. HuiC.W. LinC.S.K. McKayG. Aqueous mercury adsorption by activated carbons.Water Res.201573375510.1016/j.watres.2015.01.018 25644627
     [Google Scholar]
  53. AwesH. ZakiZ. AbbasS. DessoukiiH. ZaherA. Abd-El MoatyS.A. ShehataN. FarghaliA. MahmoudR.K. Removal of Cu2+ metal ions from water using Mg-Fe layered double hydroxide and Mg-Fe LDH/5-(3-nitrophenyllazo)-6-aminouracil nanocomposite for enhancing adsorption properties.Environ. Sci. Pollut. Res. Int.20212834476514766710.1007/s11356‑021‑13685‑0 33895951
     [Google Scholar]
  54. FengX. LongR. WangL. LiuC. BaiZ. LiuX. A review on heavy metal ions adsorption from water by layered double hydroxide and its composites.Separ. Purif. Tech.202228412009910.1016/j.seppur.2021.120099
     [Google Scholar]
  55. MondalD.K. NandiB.K. PurkaitM.K. Removal of mercury (II) from aqueous solution using bamboo leaf powder: Equilibrium, thermodynamic and kinetic studies.J. Environ. Chem. Eng.20131489189810.1016/j.jece.2013.07.034
     [Google Scholar]
  56. ZubairM. DaudM. McKayG. ShehzadF. Al-HarthiM.A. Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation.Appl. Clay Sci.201714327929210.1016/j.clay.2017.04.002
     [Google Scholar]
  57. MoghaddamH.K. PakizehM. Experimental study on mercury ions removal from aqueous solution by MnO2/CNTs nanocomposite adsorbent.J. Ind. Eng. Chem.20152122122910.1016/j.jiec.2014.02.028
     [Google Scholar]
  58. SunY. LouZ. YuJ. ZhouX. LvD. ZhouJ. BaigS.A. XuX. Immobilization of mercury (II) from aqueous solution using Al2O3-supported nanoscale FeS.Chem. Eng. J.201732348349110.1016/j.cej.2017.04.095
     [Google Scholar]
  59. ParkJ.H. WangJ.J. XiaoR. PenskyS.M. KongchumM. DeLauneR.D. SeoD.C. Mercury adsorption in the Mississippi River deltaic plain freshwater marsh soil of Louisiana Gulf coastal wetlands.Chemosphere201819545546210.1016/j.chemosphere.2017.12.104 29274991
     [Google Scholar]
  60. ArshadiM. MousaviniaF. Khalafi-NezhadA. FirouzabadiH. AbbaspourradA. Adsorption of mercury ions from wastewater by a hyperbranched and multi-functionalized dendrimer modified mixed-oxides nanoparticles.J. Colloid Interface Sci.201750529330610.1016/j.jcis.2017.05.052 28582722
     [Google Scholar]
  61. LiZ. WuL. LiuH. LanH. QuJ. Improvement of aqueous mercury adsorption on activated coke by thiol-functionalization.Chem. Eng. J.201322892593410.1016/j.cej.2013.05.063
     [Google Scholar]
  62. ChenP.H. HsuC.F. TsaiD.D.W. LuY.M. HuangW.J. Adsorption of mercury from water by modified multi-walled carbon nanotubes: Adsorption behaviour and interference resistance by coexisting anions.Environ. Technol.201435151935194410.1080/09593330.2014.886627 24956787
     [Google Scholar]
  63. ArshadiM. AmiriM.J. MousaviS. Kinetic, equilibrium and thermodynamic investigations of Ni(II), Cd(II), Cu(II) and Co(II) adsorption on barley straw ash.Water Resour. Ind.2014611710.1016/j.wri.2014.06.001
     [Google Scholar]
  64. GilesC. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface area of solids.J. Chem. Soc.196039733993
     [Google Scholar]
  65. BaoW. ZouH. GanS. XuX. JiG. ZhengK. Adsorption of heavy metal ions from aqueous solutions by zeolite based on oil shale ash: Kinetic and equilibrium studies.Chem. Res. Chin. Univ.201329112613110.1007/s40242‑013‑2139‑2
     [Google Scholar]
  66. GirishC. Various isotherm models for multicomponent adsorption: A review.Int. J. Civ. Eng. Technol20178108086
     [Google Scholar]
  67. YangS.C. LiaoY. KarthikeyanK.G. PanX.J. Mesoporous cellulose-chitosan composite hydrogel fabricated via the co-dissolution-regeneration process as biosorbent of heavy metals.Environ. Pollut.202128611732410.1016/j.envpol.2021.117324 33990049
     [Google Scholar]
  68. ChenZ. WangY-F. ZengJ. ZhangY. ZhangZ-B. ZhangZ-J. MaS. TangC-M. XuJ-Q. Chitosan/polyethyleneimine magnetic hydrogels for adsorption of heavy metal ions.Iran. Polym. J.202231101273128210.1007/s13726‑022‑01075‑3
     [Google Scholar]
  69. SahmouneM.N. Evaluation of thermodynamic parameters for adsorption of heavy metals by green adsorbents.Environ. Chem. Lett.201917269770410.1007/s10311‑018‑00819‑z
     [Google Scholar]
  70. ZhaoJ. HuangQ. LiuM. DaiY. ChenJ. HuangH. WenY. ZhuX. ZhangX. WeiY. Synthesis of functionalized MgAl-layered double hydroxides via modified mussel inspired chemistry and their application in organic dye adsorption.J. Colloid Interface Sci.201750516817710.1016/j.jcis.2017.05.087 28577466
     [Google Scholar]
  71. SalehT.A. SarıA. TuzenM. Optimization of parameters with experimental design for the adsorption of mercury using polyethylenimine modified-activated carbon.J. Environ. Chem. Eng.2017511079108810.1016/j.jece.2017.01.032
     [Google Scholar]
  72. NasirimoghaddamS. ZeinaliS. SabbaghiS. Chitosan coated magnetic nanoparticles as nano-adsorbent for efficient removal of mercury contents from industrial aqueous and oily samples.J. Ind. Eng. Chem.201527798710.1016/j.jiec.2014.12.020
     [Google Scholar]
  73. SarkarD. EssingtonM.E. MisraK.C. Adsorption of Mercury(II) by Kaolinite.Soil Sci. Soc. Am. J.20006461968197510.2136/sssaj2000.6461968x
     [Google Scholar]
  74. KadariM. MakhloufM. Graphene oxide (GO): Synthesis, characterization and application to the retention of mercuric ions in aqueous solutions.Mater. Today Proc.2022491093110410.1016/j.matpr.2021.09.426
     [Google Scholar]
  75. RihabR. HamzaS. MohamedK. Synthesis of hybrid materials and application to the retention of some effluents.Mater. Today Proc.2022491003100710.1016/j.matpr.2021.08.116
     [Google Scholar]
  76. AsasianN. KaghazchiT. FaramarziA. Hakimi-SiboniA. Asadi-KeshehR. KavandM. MohtashamiS-A. Enhanced mercury adsorption capacity by sulfurization of activated carbon with SO2 in a bubbling fluidized bed reactor.J. Taiwan Inst. Chem. Eng.20144541588159610.1016/j.jtice.2013.10.012
     [Google Scholar]
  77. ShadbadM.J. MohebbiA. SoltaniA. Mercury(II) removal from aqueous solutions by adsorption on multi-walled carbon nanotubes.Korean J. Chem. Eng.20112841029103410.1007/s11814‑010‑0463‑5
     [Google Scholar]
  78. ZhangY. YanL. XuW. GuoX. CuiL. GaoL. WeiQ. DuB. Adsorption of Pb(II) and Hg(II) from aqueous solution using magnetic CoFe2O4-reduced graphene oxide.J. Mol. Liq.201419117718210.1016/j.molliq.2013.12.015
     [Google Scholar]
  79. NakayamaH. HiramiS. TsuhakoM. Selective adsorption of mercury ion by mercaptocarboxylic acid intercalated Mg–Al layered double hydroxide.J. Colloid Interface Sci.2007315117718310.1016/j.jcis.2007.06.036 17631306
     [Google Scholar]
  80. ShamsayeiM. YaminiY. AsiabiH. Evaluation of reusable organic-inorganic nafion/layered double hydroxide nanohybrids for highly efficient uptake of mercury ions from aqueous solution.Appl. Clay Sci.201816253454210.1016/j.clay.2018.05.022
     [Google Scholar]
  81. WangL. WangM. LiZ. GongY. Enhanced removal of trace mercury from surface water using a novel Mg2Al layered double hydroxide supported iron sulfide composite.Chem. Eng. J.202039312463510.1016/j.cej.2020.124635
     [Google Scholar]
  82. MishraG. DashB. SethiD. PandeyS. MishraB.K. Orientation of organic anions in Zn-Al layered double hydroxides with enhanced antibacterial property.Environ. Eng. Sci.201734751652710.1089/ees.2016.0531
     [Google Scholar]
  83. NaikM.M. NaikH.S.B. NagarajuG. VinuthM. VinuK. RashmiS.K. Effect of aluminium doping on structural, optical, photocatalytic and antibacterial activity on nickel ferrite nanoparticles by sol–gel auto-combustion method.J. Mater. Sci. Mater. Electron.20182923203952041410.1007/s10854‑018‑0174‑y
     [Google Scholar]
  84. KarthikK. DhanuskodiS. KumarP.S. GobinathC. SivaramakrishnanS. Microwave assisted green synthesis of MgO nanorods and their antibacterial and anti-breast cancer activities.Mater. Lett.201720621722010.1016/j.matlet.2017.07.004
     [Google Scholar]
  85. StanićV. DimitrijevićS. Antić-StankovićJ. MitrićM. JokićB. PlećašI.B. RaičevićS. Synthesis, characterization and antimicrobial activity of copper and zinc-doped hydroxyapatite nanopowders.Appl. Surf. Sci.2010256206083608910.1016/j.apsusc.2010.03.124
     [Google Scholar]
  86. YuY. JinG. XueY. WangD. LiuX. SunJ. Multifunctions of dual Zn/Mg ion co-implanted titanium on osteogenesis, angiogenesis and bacteria inhibition for dental implants.Acta Biomater.20174959060310.1016/j.actbio.2016.11.067 27915020
     [Google Scholar]
  87. LotzA. HellerM. DohmN. CierniakP. BenderK. JansenB. FörchR. Antimicrobial efficacy and optimized cell adhesion from defined plasma polymerised multilayer structures involving zinc acetylacetonate and allylamine.J. Mater. Chem.20122237194551946110.1039/c2jm30344b
     [Google Scholar]
  88. SchwartzV.B. ThétiotF. RitzS. PützS. ChoritzL. LappasA. FörchR. LandfesterK. JonasU. Antibacterial surface coatings from zinc oxide nanoparticles embedded in poly (n‐isopropylacrylamide) hydrogel surface layers.Adv. Funct. Mater.201222112376238610.1002/adfm.201102980
     [Google Scholar]
  89. LiuP. ZhaoY. YuanZ. DingH. HuY. YangW. CaiK. Construction of Zn-incorporated multilayer films to promote osteoblasts growth and reduce bacterial adhesion.Mater. Sci. Eng. C201775998100510.1016/j.msec.2017.03.020 28415556
     [Google Scholar]
  90. PengF. WangD. ZhangD. CaoH. LiuX. The prospect of layered double hydroxide as bone implants: A study of mechanical properties, cytocompatibility and antibacterial activity.Appl. Clay Sci.201816517918710.1016/j.clay.2018.08.020
     [Google Scholar]
  91. MishraG. DashB. PandeyS. Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials.Appl. Clay Sci.201815317218610.1016/j.clay.2017.12.021
     [Google Scholar]
  92. GodaE.S. Abu ElellaM.H. SohailM. SinguB.S. PanditB. El ShafeyA.M. AboraiaA.M. GamalH. HongS.E. YoonK.R. N-methylene phosphonic acid chitosan/graphene sheets decorated with silver nanoparticles as green antimicrobial agents.Int. J. Biol. Macromol.202118268068810.1016/j.ijbiomac.2021.04.024 33838196
     [Google Scholar]
  93. ZhangX. LiY. GuoM. JinT.Z. ArabiS.A. HeQ. IsmailB.B. HuY. LiuD. Antimicrobial and UV blocking properties of composite chitosan films with curcumin grafted cellulose nanofiber.Food Hydrocoll.202111210633710.1016/j.foodhyd.2020.106337
     [Google Scholar]
  94. MiyataS. The syntheses of hydrotalcite-like compounds and their structures and physico-chemical properties—I: The systems Mg2+ -Al3+ -NO3−, Mg2+ -Al3+ -Cl−, Mg2+ -Al3+ -ClO4−, Ni2+ -Al3+ -Cl− and Zn2+ -Al3+ -Cl−.Clays Clay Miner.197523536937510.1346/CCMN.1975.0230508
     [Google Scholar]
  95. TheissF.L. AyokoG.A. FrostR.L. Synthesis of layered double hydroxides containing Mg2+, Zn2+, Ca2+ and Al3+ layer cations by co-precipitation methods—A review.Appl. Surf. Sci.201638320021310.1016/j.apsusc.2016.04.150
     [Google Scholar]
/content/journals/cgc/10.2174/0122133461361984250414155355
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Synthesis of 2-(Bis(Phosphonomethyl)Amino)Ethane-1-sulfonic Acid Intercalated ZnAl Layered Double Hydroxide as an Efficient Adsorbent for Hg2+ Ions and Antimicrobial Agent
Curr Green Chem 13, 196 (2026); https://doi.org/10.2174/0122133461361984250414155355
/content/journals/cgc/10.2174/0122133461361984250414155355
/content/journals/cgc/10.2174/0122133461361984250414155355
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  • Article Type:     Research Article
Keyword(s): adsorption tests; aqueous solution; environmental remediation; fungus; hydrotalcites; Mercury removal; phosphonic acid

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