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Background and Objective: Zwitterionic polymer electrolyte has been successfully synthesized using NH4PF6 salt. The conductivity of the synthesized polymer membrane is found to be of the order of 10-3 Scm-1. Dielectric and Modulus properties of the polymer electrolyte have also been studied which shows well relaxation peaks with both temperature and salt concentrations. Results: Debye type relaxation behavior has observed from the electric modulus. Conclusion: Frequency dependent conductivity data (fitted with Jonscher's power law equation) confirmed the presence of NCL/SLPL type behavior in the studied frequency range.