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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Transition Metal-free Trifluoroethoxylation of Diaryliodonium Salts and Fluoro Alcohols
- Source: Letters in Organic Chemistry, Volume 16, Issue 6, Jun 2019, p. 485 - 490
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- 01 Jun 2019
Abstract
A method for the synthesis of aryl trifluoroethyl ethers from fluoroalcohols and diaryliodonium salts in the presence of NaH and warm 1,2-dichloroethane has been developed. This transition metal free reaction is mild and facile. Various functional group including electron-withdrawing and electron-donating substrates in the diaryliodonium salts were tolerated in this transformation to afford the products in moderate to high yields.
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