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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System
- Source: Letters in Organic Chemistry, Volume 15, Issue 12, Dec 2018, p. 1042 - 1045
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- 01 Dec 2018
Abstract
Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp = cyclopentadienyl) under solventfree conditions has been investigated. The mole ratio of Cp2TiCl2/Sm has some influence on the catalytic properties, and the best Cp2TiCl2/Sm ratio for the catalytic hydrosilylation is 1/2. By using this catalytic system, hydrogenation products were also detected in the final reaction mixtures.
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