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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Iodine Mediated Addition of Trialkylamines to Dimethyl Acetylenedicarboxylate
- Source: Letters in Organic Chemistry, Volume 10, Issue 9, Nov 2013, p. 617 - 621
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- 01 Nov 2013
Abstract
Addition reaction of tertiary amines to dimethyl acetylenedicarboxylate mediated by molecular iodine is described. The trialkylamines afford dealkylative adducts in moderate to good yields. Amines containing an aryl group react sluggishly in low yields with a loss of alkyl group.
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