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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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The Synthesis, Reactivity and NMR Investigation on 15N-Thiophosphoramidates (Supplementary Material)
- Source: Letters in Organic Chemistry, Volume 6, Issue 8, Dec 2009, p. 642 - 647
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- 01 Dec 2009
Abstract
Novel 15N-isotope enriched potassium and diammonium thiophosphoramidates were synthesized and their spectroscopic properties, along with reactivity towards several compounds, including histidine, thymidine, glucose and 2- deoxyribose are presented. The application of quantum mechanical DFT calculations for estimation of 31P NMR chemical shifts for several thiophosphoramidate ions and its derivatives are also discussed.
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