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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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One-Pot Rapid and Efficient Synthesis of Gem-Bisallylated Alcohols Mediated by Zinc-Copper Couple under Solvent-free Conditions
- Source: Letters in Organic Chemistry, Volume 5, Issue 8, Dec 2008, p. 669 - 671
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- 01 Dec 2008
Abstract
An efficient and rapid procedure for the conversion of various carboxylic acid derivatives into the corresponding gem-bisallylated compounds under mild reaction conditions has been developed. Zinc-copper couple mediating Barbier- type addition of carboxylic acid derivative was utilized as a key operation to affect the transformation. The procedure is operationally simple, giving good to high product yield.
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