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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Glycosidation Reactions of 5-Thioxylopyranosyl Donors
- Source: Letters in Organic Chemistry, Volume 5, Issue 6, Sep 2008, p. 429 - 431
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- 01 Sep 2008
Abstract
Glycosidation reactions of 5-thioxylopyranosides were examined. The reaction of a 1,5-dithioxyloside derivative with N-iodosuccinimide and trifluoromethanesulfonate gave ring-opened products, but no glycosylated products. On the other hand, a 5-thioxylopyranosyl trichloroacetimidate derivative was found to react with aliphatic alcohols and a sugar alcohol to give a 5-thio analog of biologically important β(1,4)xylopyranoside structures.
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