Study on Host-Guest Complexation of Anions Based on 2,2'-Dihydroxyl-1,1'-Binaphtalene Derivatives

Kazuaki Ito; Mio Takahashi; Takuya Hoshino; Makoto Nishiki; Yoshihiro Ohba

doi:10.2174/157017806779025898

ISSN: 1570-1786
E-ISSN: 1875-6255

Study on Host-Guest Complexation of Anions Based on 2,2'-Dihydroxyl-1,1'-Binaphtalene Derivatives
Authors: Kazuaki Ito¹, Mio Takahashi², Takuya Hoshino³, Makoto Nishiki⁴ and Yoshihiro Ohba⁵
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¹ Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510, Japan. ² Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510, Japan. ³ Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510, Japan. ⁴ Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510, Japan. ⁵ Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510, Japan.
Source: Letters in Organic Chemistry, Volume 3, Issue 10, Oct 2006, p. 735 - 740
DOI: https://doi.org/10.2174/157017806779025898
- Available online: 01 Oct 2006

Abstract

The anion binding properties of 2,2'-dihydroxyl-1,1'-binaphtalene (BINOL) derivatives were studied by 1H NMR spectroscopy. BINOL derivatives formed the complex with anions through hydrogen bonding using hydroxyl groups and showed a binding preference to dihydrogen phosphate (H2PO4 -) and acetate (CH3CO2-) in comparison with other anions (Cl-, Br-, I-, NO3-, and HSO4-) tested.

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2006-10-01

2025-09-15

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Article Type: Research Article

Keyword(s): 1'-binaphtalene; 2,2'-dihydroxyl-1; Anion recognition; hydrogen bonding; hydroxyl group; quaternary ammonium salt

Study on Host-Guest Complexation of Anions Based on 2,2'-Dihydroxyl-1,1'-Binaphtalene Derivatives

Abstract

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