Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

M. Shimizu; S. Itohara

doi:10.2174/157017805774296902

ISSN: 1570-1786
E-ISSN: 1875-6255

Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate
Authors: M. Shimizu¹ and S. Itohara²
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¹ Department of Chemistry for Materials, Mie University, Tsu, Mie 514-8507, Japan. ² Department of Chemistry for Materials, Mie University, Tsu, Mie 514-8507, Japan.
Source: Letters in Organic Chemistry, Volume 2, Issue 7, Nov 2005, p. 648 - 651
DOI: https://doi.org/10.2174/157017805774296902
- Available online: 01 Nov 2005

Abstract

An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enones gave 4-alkoxy-1,5-diketones in good yields.

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2005-11-01

2025-10-27

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Article Type: Review Article

Keyword(s): alkoxyacetone; alkoxyallene oxide; conjugate addition; titanium tetraiodide

Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

Abstract

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