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- ISSN: 1570-1786
- E-ISSN: 1875-6255
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Introduction of a Benzoquinone Pharmacophore on a Labdane Platform
- Source: Letters in Organic Chemistry, Volume 2, Issue 6, Sep 2005, p. 515 - 517
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- 01 Sep 2005
Abstract
The allylic alcohol of the side-chain of larixol was converted into an exo 1,3-diene through trifluoroacetylation followed by palladium-catalyzed elimination; this allowed the introduction of a benzoquinone pharmacophore on this labdane platform in 'one-pot' from allylic trifluoroacetates.
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