Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics

Fahim Ahmed; Yeyu Cao; William A. Donaldson

doi:10.2174/1570178053765366

ISSN: 1570-1786
E-ISSN: 1875-6255

Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics
Authors: Fahim Ahmed¹, Yeyu Cao² and William A. Donaldson³
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¹ Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, WI 53201-1881, USA. ² Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, WI 53201-1881, USA. ³ Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, WI 53201-1881, USA.
Source: Letters in Organic Chemistry, Volume 2, Issue 3, May 2005, p. 222 - 225
DOI: https://doi.org/10.2174/1570178053765366
- Available online: 01 May 2005

Abstract

Methodology for preparation of the C8-C16 dienylamine segment of the streptogramin antibiotics is based on a diastereoselective nitrile oxide-olefin cycloaddition to a (triene)iron complex. The Fe(CO)3 adjunct also serves as a protecting group for the subsequent reductive hydrolysis of the isoxazoline ring.

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2005-05-01

2025-10-26

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Article Type: Review Article

Keyword(s): (diene)iron complexes; cyclocondensation; streptogramin antibiotics

Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics

Abstract

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