Full text loading...
- ISSN: 1570-1786
- E-ISSN: 1875-6255
-
Metal Mediated Dechlorination - A New Route to Nitriles
- Source: Letters in Organic Chemistry, Volume 1, Issue 1, Jan 2004, p. 40 - 42
-
- 01 Jan 2004
Abstract
1,4-Dichloro-1,4-disubstituted-2,3-diaza-1,3-butadiene 1 undergo cyclodechlorination in presence of Be metal to form cyclazines 3a. Reaction of 1 with Cu, Zn and Mn metals results in formation of nitriles 2. Cyclazines 3 on further oxidation with H2O2 in CH3COOH form NO donors, 1,2-dioxides 4.
© Bentham Science Publishers