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2000
Volume 12, Issue 1
  • ISSN: 2213-3356
  • E-ISSN: 2213-3364

Abstract

Background

Synthetic dye removal from wastewater poses significant environmental challenges. Metal-organic Frameworks (MOFs), like ZIF-8, offer potential solutions due to their high adsorption capacities. This study has investigated the efficacy of a novel composite material, α-AlO@ZIF-8, for Methylene Blue (MB) removal.

Objective

This study aimed to assess the feasibility of α-AlO@ZIF-8 for MB removal. The synthesis microwave-assisted methods, physicochemical characterization, adsorption efficiency evaluation, and isothermal/kinetic modeling, has been conducted.

Methods

The α-AlO@ZIF-8 composite was synthesized and characterized using SEM, TEM, FTIR, and BET techniques. The adsorption efficiency for MB was tested, and isothermal/kinetic models were applied for mechanistic understanding.

Results

The composite exhibited robust crystal connections and uniform distribution, with particle sizes ranging from 0.5 to 0.6 µm. MB adsorption efficiency exceeded 97.8% under optimal conditions. Isothermal and kinetic modeling revealed favorable adsorption behavior, notably with the Langmuir and pseudo-second-order models.

Conclusion

Microwave-synthesized α-AlO@ZIF-8 shows promise for efficient MB removal, with treatment efficiencies surpassing 97%. This underscores the potential of MOFs in wastewater treatment and emphasizes the importance of understanding adsorption mechanisms for optimization.

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2024-08-22
2025-09-02
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References

  1. ParmarS. DakiS. BhattacharyaS. ShrivastavA. Microorganism: An ecofriendly tool for waste management and environmental safety. Development in wastewater treatment research and processes.AmsterdamElsevier202217519310.1016/B978‑0‑323‑85657‑7.00001‑8
    [Google Scholar]
  2. CarmenZ. DanielaS. Textile organic dyes-characteristics, polluting effects and separation/elimination procedures from industrial effluents-a critical overview.Organic Pollutants Ten Years After the Stockholm Convention - Environmental and Analytical UpdateInTechOpenLondon201210.5772/32373
    [Google Scholar]
  3. Ardila-LealL.D. Poutou-PiñalesR.A. Pedroza-RodríguezA.M. Quevedo-HidalgoB.E. A brief history of colour, the environmental impact of synthetic dyes and removal by using laccases.Molecules20212613381310.3390/molecules26133813 34206669
    [Google Scholar]
  4. DoD.D. BuiH.M. TranC.S. Residue fluidized catalytic cracking in lightweight polystyrene concrete: A sustainable construction solution.Sustain Chem One World2024110000310.1016/j.scowo.2024.100003
    [Google Scholar]
  5. VuongT.K. BuiH.M. The effect of branding, perceived environmental and social responsibility on customer satisfaction and loyalty.Pol. J. Environ. Stud.20233265811582310.15244/pjoes/169895
    [Google Scholar]
  6. Al-TohamyR. AliS.S. LiF. OkashaK.M. MahmoudY.A.G. ElsamahyT. JiaoH. FuY. SunJ. A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety.Ecotoxicol. Environ. Saf.202223111316010.1016/j.ecoenv.2021.113160 35026583
    [Google Scholar]
  7. SadeghH. AliG. Potential Applications of Nanomaterials in Wastewater Treatment: Nanoadsorbents Performance. AssociationI.R.M. Pennsylvania, United StatesIGI global201812301240
    [Google Scholar]
  8. LiX. FuL. ChenF. ZhaoS. ZhuJ. YinC. Application of heterogeneous catalytic ozonation in wastewater treatment: an overview.Catalysts202313234210.3390/catal13020342
    [Google Scholar]
  9. PlengplungP. RatanatawanateC. DubasS.T. Improved stability of zeolitic imidazolate framework-8 photocatalytic coating on polyurethane foam via polyelectrolyte multilayer surface modification.Colloids Surf. A Physicochem. Eng. Asp.202162912741510.1016/j.colsurfa.2021.127415
    [Google Scholar]
  10. PourmortazaviS.M. SahebiH. ZandavarH. MirsadeghiS. Fabrication of Fe3O4 nanoparticles coated by extracted shrimp peels chitosan as sustainable adsorbents for removal of chromium contaminates from wastewater: The design of experiment.Compos., Part B Eng.201917510713010.1016/j.compositesb.2019.107130
    [Google Scholar]
  11. RashadM. Abd-ElnaiemA.M. HanafyT.A. ShaalanN.M. ShamekhA.M.A. Optical properties of functional Al2O3 nano-filler in eco-friendly PVA polymer for flexible optoelectronic devices.Opt. Mater.202314111399010.1016/j.optmat.2023.113990
    [Google Scholar]
  12. SangorF.I.M.S. Al-GhoutiM.A. Waste-to-value: Synthesis of nano-aluminum oxide (nano-γ-Al2O3) from waste aluminum foils for efficient adsorption of methylene blue dye.Case Stud Chem Environ Eng2023810039410.1016/j.cscee.2023.100394
    [Google Scholar]
  13. AkhundzadehT.A. HalladjR. AskariS. Different view of solvent effect on the synthesis methods of zeolitic imidazolate framework-8 to tuning the crystal structure and properties.RSC Advances20211132199141992310.1039/D1RA02856A 35479238
    [Google Scholar]
  14. Bazan-WozniakA. MachelakK. Nosal-WiercińskaA. PietrzakR. Microwave heating for synthesis of carbonaceous adsorbents for removal of toxic organic and inorganic contaminants.Molecules20232819682510.3390/molecules28196825 37836668
    [Google Scholar]
  15. AuliaW. AhnafA. IriantoM.Y. EdiatiR. IqbalR.M. RachmanR.A. MartiaU.T.I. Synthesis and characterization of zeolitic imidazolate framework-8 (ZIF-8)/Al2O3 composite.IPTEK The J Technol Sci20203111810.12962/j20882033.v31i1.5511
    [Google Scholar]
  16. Valadez SánchezE.P. GliemannH. Haas-SantoK. DingW. HansjostenE. WohlgemuthJ. WöllC. DittmeyerR. α-Al2O3-supported ZIF-8 SURMOF membranes: Diffusion mechanism of ethene/ethane mixtures and gas separation performance.J. Membr. Sci.202059411742110.1016/j.memsci.2019.117421
    [Google Scholar]
  17. BanihashemiF. LinJ.Y.S. Synthesis of ZIF-8 membranes on γ-alumina supports for separation of propylene/propane gas mixture.Ind. Eng. Chem. Res.202261114125413310.1021/acs.iecr.1c04986
    [Google Scholar]
  18. KalamS. Abu-KhamsinS.A. KamalM.S. PatilS. Surfactant Adsorption Isotherms: A Review.ACS Omega2021648323423234810.1021/acsomega.1c04661 34901587
    [Google Scholar]
  19. El-NemrM.A. YılmazM. RagabS. El NemrA. Biochar-SO prepared from pea peels by dehydration with sulfuric acid improves the adsorption of Cr6+ from water.Biomass Convers. Biorefin.20241422601261910.1007/s13399‑022‑02378‑4
    [Google Scholar]
  20. ChenX. HossainM.F. DuanC. LuJ. TsangY.F. IslamM.S. ZhouY. Isotherm models for adsorption of heavy metals from water - A review.Chemosphere2022307Pt 113554510.1016/j.chemosphere.2022.135545 35787879
    [Google Scholar]
  21. BonelliB. FreyriaF.S. RossettiI. SethiR. SahooT.R. PrelotB. Eds.; Adsorption processes for the removal of contaminants from wastewater: The perspective role of nanomaterials and nanotechnology.Nanomaterials for the Detection and Removal of Wastewater PollutantsElsevier: Amsterdam202016122210.1016/B978‑0‑12‑818489‑9.00007‑4
    [Google Scholar]
  22. HillmanF. ZimmermanJ.M. PaekS.M. HamidM.R.A. LimW.T. JeongH.K. Rapid microwave-assisted synthesis of hybrid zeolitic–imidazolate frameworks with mixed metals and mixed linkers.J. Mater. Chem. A Mater. Energy Sustain.20175136090609910.1039/C6TA11170J
    [Google Scholar]
  23. YooH. ShinN. Fabrication of well-intergrown ZIF-8 films via sequential ZnO seed layer overlaying.Appl. Surf. Sci.202362515721110.1016/j.apsusc.2023.157211
    [Google Scholar]
  24. SantosoE. EdiatiR. IstiqomahZ. SulistionoD.O. NugrahaR.E. KusumawatiY. BahrujiH. PrasetyokoD. Facile synthesis of ZIF-8 nanoparticles using polar acetic acid solvent for enhanced adsorption of methylene blue.Microporous Mesoporous Mater.202131011062010.1016/j.micromeso.2020.110620
    [Google Scholar]
  25. LeeJ.H. KimD. ShinH. YooS.J. KwonH.T. KimJ. Zeolitic imidazolate framework ZIF-8 films by ZnO to ZIF-8 conversion and their usage as seed layers for propylene-selective ZIF-8 membranes.J. Ind. Eng. Chem.20197237437910.1016/j.jiec.2018.12.039
    [Google Scholar]
  26. KangD.A. JeongH.K. Enhancing the C3 separation performances of polycrystalline ZIF-8 membranes by additive-assisted secondary growth.J. Membr. Sci.202367712159310.1016/j.memsci.2023.121593
    [Google Scholar]
  27. Teğinİ. ÖcS. SakaC. Adsorption of copper (II) from aqueous solutions using adsorbent obtained with sodium hydroxide activation of biochar prepared by microwave pyrolysis.Biomass Convers. Biorefin.20242024610.1007/s13399‑024‑05477‑6
    [Google Scholar]
  28. DimboD. Methylene blue adsorption from aqueous solution using activated carbon of spathodea campanulata.Results Eng.202421101910
    [Google Scholar]
  29. EbrahimiP. KumarA. Diatomite chemical activation for effective adsorption of methylene blue dye from model textile wastewater.Int. J. Environ. Sci. Develop2021122328
    [Google Scholar]
  30. AhmadA. MartsinovichN. Modelling the strength of mineral-organic binding: Organic molecules on the α-Al2O3(0001) surface.RSC Advances202212422760427615 36276046
    [Google Scholar]
  31. ChaB.J. WooT.G. ParkE.J. KimI.H. AnJ.E. SeoH.O. KimY.D. Photo-catalytic activity of hydrophilic-modified TiO 2 for the decomposition of methylene blue and phenol.Curr. Appl. Phys.201717111557156310.1016/j.cap.2017.07.002
    [Google Scholar]
  32. GenelY. Genelİ. SakaC. Facile preparation of sulfonated carbon particles with pomegranate peels as adsorbent for enhanced methylene blue adsorption from aqueous solutions.Biomass Convers. Biorefin.20242024410.1007/s13399‑024‑05328‑4
    [Google Scholar]
  33. BazziL. AyouchI. TachallaitH.E.L. HankariS. Ultrasound and microwave assisted-synthesis of ZIF-8 from zinc oxide for the adsorption of phosphate.Results Eng.20221310037810.1016/j.rineng.2022.100378
    [Google Scholar]
  34. DuP.D. HieuN.T. ThienT.V. Ultrasound-assisted rapid ZIF-8 synthesis, porous ZnO preparation by heating ZIF-8, and their photocatalytic activity.J. Nanomater.2021202111210.1155/2021/9988998
    [Google Scholar]
  35. AlinejadA. SadeghiS. GhaderpooriM. SahebiS. GhaderpouryA. MohammadiA.A. SaghiM.H. GholampourY. KhaniJ.A. High adsorption of methylene blue from aqueous solutions using leaf-shaped ZIF-8.Int. J. Environ. Anal. Chem.2021101142354236710.1080/03067319.2019.1702170
    [Google Scholar]
  36. ZhengJ. ChengC. FangW.J. ChenC. YanR.W. HuaiH.X. WangC-C. Surfactant-free synthesis of a Fe3O4@ZIF-8 core–shell heterostructure for adsorption of methylene blue.CrystEngComm201416193960396410.1039/c3ce42648c
    [Google Scholar]
  37. MazlanN.A. ButtF.S. LewisA. KrishnamoorthiR. ChenS. RadacsiN. HuangY. Robust reduced graphene oxide-PDA/ZIF-8 aerogel composite for cyclic, high-capacity dye adsorption.Separ. Purif. Tech.202433412600510.1016/j.seppur.2023.126005
    [Google Scholar]
  38. WuG. ZhouC. LiH. XiaS. ZhuY. HanJ. XingW. Controlled fabrication of the biomass cellulose aerogel@ZIF-8 nanocomposite as efficient and recyclable adsorbents for methylene blue removal.Ind. Crops Prod.202319311616910.1016/j.indcrop.2022.116169
    [Google Scholar]
  39. ÖzdemirM. DurmuşÖ. ŞahinÖ. SakaC. Removal of methylene blue, methyl violet, rhodamine B, alizarin red, and bromocresol green dyes from aqueous solutions on activated cotton stalks.Desal Water Treat.20165738180381804810.1080/19443994.2015.1085916
    [Google Scholar]
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  • Article Type:
    Research Article
Keyword(s): composite material; Dye removal; metal-organic frameworks; methylene blue; ZIF-8; α-Al2O3
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