Synthesis of Chiral Fluorinated Materials via Biotransformation
- Authors: Tomoya Kitazume1, Tomoko Matsuda2, Kaoru Nakamuraa3
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View Affiliations Hide Affiliations1 Department of Bioengineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori ku, Yokohama 226-8501, Japan. 2 Department of Bioengineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori ku, Yokohama 226-8501, Japan. 3 Department of Bioengineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori ku, Yokohama 226-8501, Japan.
- Source: Advances in Organic Synthesis: Volume 2 , pp 463-490
- Publication Date: January 2006
- Language: English
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Biotransformation of organofluorine materials into the optically active functionalized fluorinated materials along with the discussion on the effect of fluorine atom(s) during the enantioselective and/or diastereoselective transformations is described. The ability of microorganism to discriminate between enantiomers is very important for the purpose of resolution and asymmetric synthesis. Also included are discussions on recent developments in methodologies to control enantioselectivities of catalytic reactions. Examples of practical applications that involve reduction of various types of ketones are also included.
Hardbound ISBN:
9781608056446
Ebook ISBN:
9781608051984
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