Skip to content
2000
image of Semi-Empirical Analysis of Polyamide 11 Hybrid Composites: Unveiling the Journey from Simple Models to Complex Theories

Abstract

Introduction

Predicting the properties of hybrid composites is challenging
due to their mechanical and thermal heterogeneity, anisotropy, and complex 
microstructures. This has led to the development of various theoretical models, each 
tailored to assess specific microstructures and optimize material properties for targeted 
applications.

Methods

The present paper presents a semi-empirical analysis of hybrid Polyamide 11 (PA11) composites reinforced with wood and carbon fibers. To predict the tensile modulus of natural fiber composites, methods such as ROM, IROM, Halpin-Tsai, Halpin-Tsai for random fiber orientations, and shear lag model equations were employed and accordingly modified. Employing the “effective matrix” approach, the modified single fiber system equations were further employed for hybrid fiber systems. The HROM, Halpin-Tsai, Halpin-Tsai for random fiber orientations, Halpin-Tsai for hybrid composites, and shear lag model equations were applied and modified for hybrid composites.

Results and Discussion

The Halpin-Tsai equations for randomly distributed fibers demonstrated the highest level of agreement with the experimental findings. The best-fit values for λ 
(longitudinal direction) and λ (Transverse direction) for randomly distributed fibers in 
Halpin-Tsai models were 0.372 and 0.568. These values were in excellent agreement with
the original Halpin-Tsai equations for randomly dispersed fibers, which are reported as 0.375 and 0.625, respectively. Similarly, the experimental findings strongly correlate with the
Halpin-Tsai equations for hybrid composites documented in the literature. Furthermore, 
this study effectively derived and employed modified equations from several micromechanical models to accurately predict the tensile modulus for single and hybrid fiber-reinforced composites.

Conclusion

Hybrid composites of PA11 reinforced with natural and carbon fibers represent a promising approach for sustainable, high-performance materials. This study's experimental results closely align with several established micromechanical models, including the Halpin-Tsai model for both randomly distributed short fibers and hybrid composites. Additionally, existing models for single-fiber composites, such as ROM and shear lag theory, were effectively modified to match the study's experimental data. These modifications accounted for fiber misalignment, inadequate fiber-matrix interaction, fiber breakage, and natural fiber degradation. The modified models' predicted moduli were consistent with the experimental findings for both single-fiber and hybrid systems.

Loading

Article metrics loading...

/content/journals/caps/10.2174/0124522716358289250214072751
2025-02-18
2025-10-28
Loading full text...

Full text loading...

References

  1. Facca A.G. Kortschot M.T. Yan N. Predicting the elastic modulus of natural fibre reinforced thermoplastics. Compos., Part A Appl. Sci. Manuf. 2006 37 10 1660 1671 10.1016/j.compositesa.2005.10.006
    [Google Scholar]
  2. Banerjee S. Sankar B.V. Mechanical properties of hybrid composites using finite nlm method based micromechanics. Compos., Part B Eng. 2014 58 58 318 327 10.1016/j.compositesb.2013.10.065
    [Google Scholar]
  3. Facca A. Kortschot M. Yan N. Predicting the elastic modulus of hybrid fiber reinforced thermoplastics Polym. Compos. 2006 14 3 239
    [Google Scholar]
  4. Guedes J. Kikuchi N. Preprocessing and postprocessing for materials based on the homogenization method with adaptive finite nlm methods. Comput. Methods Appl. Mech. Eng. 1990 83 2 143 198 10.1016/0045‑7825(90)90148‑F
    [Google Scholar]
  5. Hill R. Elastic properties of reinforced solids: Some theoretical principles. J. Mech. Phys. Solids 1963 11 5 357 372 10.1016/0022‑5096(63)90036‑X
    [Google Scholar]
  6. Sun C.T. Chen J.L. A simple flow rule for characterizing nonlinear behavior of fiber composites. J. Compos. Mater. 1989 23 10 1009 1020 10.1177/002199838902301004
    [Google Scholar]
  7. Armioun S. Panthapulakkal S. Scheel J. Tjong J. Sain M. Biopolyamide hybrid composites for high performance applications. J. Appl. Polym. Sci. 2016 133 27 43595 10.1002/app.43595
    [Google Scholar]
  8. Armioun S. Panthapulakkal S. Scheel J. Tjong J. Sain M. Sustainable and lightweight biopolyamide hybrid composites for greener auto parts. Can. J. Chem. Eng. 2016 94 11 2052 2060 10.1002/cjce.22609
    [Google Scholar]
  9. Armioun S. Pervaiz M. Sain M. Biopolyamides and high-performance natural fiber-reinforced biocomposites Handbook of Composites from Renewable Materials. Wiley 2017 253 270 10.1002/9781119441632.ch49
    [Google Scholar]
  10. Smith P. Wang H. Li C. A comparative study on the mechanical, thermal, and morphological characterization of polyamide 11 composites reinforced with carbon fibers and flax fibers Compos. B. Eng. 2019 176 2 155 174
    [Google Scholar]
  11. Oliver-Ortega H. Julian F. Espinach F.X. Tarrés Q. Ardanuy M. Mutjé P. Research on the use of lignocellulosic fibers reinforced bio-polyamide 11 with composites for automotive parts: Car door handle case study. J. Clean. Prod. 2019 226 64 73 10.1016/j.jclepro.2019.04.047
    [Google Scholar]
  12. Magniez K. Iftikhar R. Fox B.L. Properties of bio-based polymer nylon 11 reinforced with short carbon fiber composites. Polym. Compos. 2015 36 4 668 674 10.1002/pc.22985
    [Google Scholar]
  13. Jones R. Mechanics of Composite Material. New York McGraw-Hill 1975
    [Google Scholar]
  14. Jones R. Mechanics of Composite Material. United States Hemisphere Publishing Corporation 1975
    [Google Scholar]
  15. Tucker C.L. III Liang E. Stiffness predictions for unidirectional short-fiber composites: Review and evaluation. Compos. Sci. Technol. 1999 59 5 655 671 10.1016/S0266‑3538(98)00120‑1
    [Google Scholar]
  16. Halpin J. Tsai S. Effects of environmental factors on composite materials. Thesis, Air Force Materials Laboratory Air Force Systems Command Wright-patterson Air Force Base, Ohio. 1969 Available from:https://apps.dtic.mil/sti/tr/pdf/ADA306357.pdf
    [Google Scholar]
  17. Affdl J.C.H. Kardos J.L. The Halpin‐Tsai equations: A review. Polym. Eng. Sci. 1976 16 5 344 352 10.1002/pen.760160512
    [Google Scholar]
  18. Ingber M.S. Papathanasiou T.D. A parallel-supercomputing investigation of the stiffness of aligned, short-fiber-reinforced composites using the Boundary nlm Method. Int. J. Numer. Methods Eng. 1997 40 18 3477 3491 10.1002/(SICI)1097‑0207(19970930)40:18<3477::AID‑NME225>3.0.CO;2‑B
    [Google Scholar]
  19. Loos M. Fundamentals of polymer matrix composites containing CNTs. Carbon Nanotube Reinforced Composites. William Andrew Publishing 2015 125 170 10.1016/B978‑1‑4557‑3195‑4.00005‑9
    [Google Scholar]
  20. Cox H.L. The elasticity and strength of paper and other fibrous materials. Br. J. Appl. Phys. 1952 3 3 72 79 10.1088/0508‑3443/3/3/302
    [Google Scholar]
  21. Facca A.G. Kortschot M.T. Yan N. Predicting the tensile strength of natural fibre reinforced thermoplastics. Compos. Sci. Technol. 2007 67 11-12 2454 2466 10.1016/j.compscitech.2006.12.018
    [Google Scholar]
  22. Krenchel H. Fiber Reinforcement. Copenhagen Akademisk Forlag 1964
    [Google Scholar]
  23. Thomason J.L. Vlug M.A. Influence of fibre length and concentration on the properties of glass fibre-reinforced polypropylene: 1. Tensile and flexural modulus. Compos., Part A Appl. Sci. Manuf. 1996 27 6 477 484 10.1016/1359‑835X(95)00065‑A
    [Google Scholar]
  24. Fu S.Y. Lauke B. Characterization of tensile behaviour of hybrid short glass fibre/calcite particle/ABS composites. Compos., Part A Appl. Sci. Manuf. 1998 29 5-6 575 583 10.1016/S1359‑835X(97)00117‑6
    [Google Scholar]
  25. Fu S.Y. Lauke B. Mäder E. Yue C-Y. Hu X. Mai Y.W. Hybrid effects on the tensile properties of hybrid short glass fiber and short carbon fiber reinforced polypropylene composites. J. Mater. Sci. 2001 36 5 1243 1251 10.1023/A:1004802530253
    [Google Scholar]
  26. Jayaraman K. Kortschot M.T. Correction to the Fukuda-Kawata Young’s modulus theory and the Fukuda-Chou strength theory for short fibre-reinforced composite materials. J. Mater. Sci. 1996 31 8 2059 2064 10.1007/BF00356627
    [Google Scholar]
  27. Fu S.Y. Xu G. Mai Y.W. On the elastic modulus of hybrid particle/short-fiber/polymer composites. Compos., Part B Eng. 2002 33 4 291 299 10.1016/S1359‑8368(02)00013‑6
    [Google Scholar]
  28. Liu C. Wang X. Wang Y. Analysis on the process of stress transferring in single fiber composite and Monte-Carlo simulation on the process of single-fiber fragmentation. J. Reinf. Plast. Compos. 2014 33 12 1105 1119 10.1177/0731684414525675
    [Google Scholar]
  29. Azeko S.T. Mensah J.K. Arthur E.K. Abiwu N. Flomo M.K. Boadu J.A. Yamba P. Larson E.A. Akayeti A. Satankar R.K. Annan E. Eco-friendly green composites reinforced with recycled polyethylene for engineering applications. J. Mater. Cycles Waste Manag. 2023 25 4 2431 2441 10.1007/s10163‑023‑01701‑z
    [Google Scholar]
  30. Hou Y. Panesar A. Effect of manufacture-induced interfaces on the tensile properties of 3D printed polyamide and short carbon fibre-reinforced polyamide composites. Polymers 2023 15 3 773 10.3390/polym15030773 36772073
    [Google Scholar]
  31. Lewis T.B. Nielsen L.E. Dynamic mechanical properties of particulate‐filled composites. J. Appl. Polym. Sci. 1970 14 6 1449 1471 10.1002/app.1970.070140604
    [Google Scholar]
  32. Liu X. Zhang Q. Lu C. Chung D. Electrical and thermal conduction in carbon fiber reinforced polyamide-11. Compos., Part A Appl. Sci. Manuf. 2017 95 229 238
    [Google Scholar]
/content/journals/caps/10.2174/0124522716358289250214072751
Loading
/content/journals/caps/10.2174/0124522716358289250214072751
Loading

Data & Media loading...

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test