Regio- and Stereoselective Ring Opening of Allylic Epoxides
- Authors: Mauro Pineschi1, Ferruccio Bertolini2, Valeria Di Bussolo3, Paolo Crotti4
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View Affiliations Hide Affiliations1 Dipartimento di Farmacia, Universit di Pisa, via Bonanno 33, 56126, Pisa, Italy 2 Dipartimento di Farmacia, Universit di Pisa, via Bonanno 33, 56126, Pisa, Italy 3 Dipartimento di Farmacia, Universit di Pisa, via Bonanno 33, 56126, Pisa, Italy 4 Dipartimento di Farmacia, Universit di Pisa, via Bonanno 33, 56126, Pisa, Italy
- Source: Advances in Organic Synthesis: Volume 5 , pp 101-184
- Publication Date: January 2013
- Language: English
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Three-membered heterocyclic rings offer a powerful combination of reactivity, stability, availability, and atom economy. In fact, the asymmetric ring opening of allylic epoxides with nucleophiles of different kinds, as will be discussed in this Review, offers the possibility of generating valuable chiral non-racemic building blocks in a very simple manner and in a stereodefined fashion.
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